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Certain graphics just look bad by nature in VGA, but there are definitely games out there you'd think would shine, but fall flat.
I'll start with Resident Evil 2. Ah, what a disappointment. Mainly it's the textures and titles going blocky, fire, blood, etc. The characters aren't too bad and the colors are quite vivid. But alas, overall it is horrible. I was excited to try it in VGA too. At least it looks awesome in s-video.
By "support" I mean it runs, not necessarily labelled as such.